Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season     

Loreto Donoso  Rodrigo Romero  Alberto Rondón  Emmanuel Fernandez  Pedro Oyola  Eugenio Sanhueza 《Journal of Atmospheric Chemistry》1996,25(2):201-214

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.  相似文献   

A Eulerian air pollution model for Europe with nonlinear chemistry   总被引：1，自引：0，他引：1  

Z. Zlatev  J. Christensen  Ø. Hov 《Journal of Atmospheric Chemistry》1992,15(1):1-37

A long-range transport model with nonlinear chemical reactions is described. The model contains 35 pollutants and 70 chemical reactions. This is a Eulerian model defined on a space domain containing the whole of Europe. The spherical space domain (corresponding to the Earth's surface covered by the model) is mapped into a square plane domain and discretized by using a 32×32 grid. The grid increments are equidistant (both along the Ox axis and along the Oy axis). The choice of values of the physical parameters involved in the model and the numerical treatment of the model are shortly discussed. The model is tested with meteorological data for 1985 and 1989. The numerical results are compared with measurements at stations located in different European countries. Extensive comparisons of ozone concentrations for July 1985 with measurements taken at 24 European stations are also carried out. Results concerning three episodes in July 1985 as well as results obtained in the study of the sensitivity of the ozone concentrations to variations of NO _x and/or anthropogenic VOC emissions are presented. The advantages and the limitations of such a model are discussed. The model is continuously improved by adding new modules to it. The plans for improvements in the near future are outlined.  相似文献   

Solar ultraviolet transfer in the Martian atmosphere: biological and geological implications     

C Córdoba-Jabonero  L.M LaraA.M Mancho  A MárquezR Rodrigo 《Planetary and Space Science》2003,51(6):399-410

  相似文献   

The Kuwae (Vanuatu) eruption of<Emphasis Type="SmallCaps"> AD</Emphasis> 1452: potential magnitude and volatile release     

J. B. Witter  S. Self 《Bulletin of Volcanology》2007,69(3):301-318

Sometime during AD 1452, according to new evidence, a large-magnitude, initially phreatomagmatic eruption, destroyed the island of Kuwae (16.83°S, 168.54°E), located in the present-day Republic of Vanuatu. It created a 12×6-km submarine caldera composed of two adjacent basins. Based on estimates of caldera volume, between 30 and 60 km³ DRE of dacite magma was ejected as pyroclastic flow and fall deposits during this event. Annual layers of ice dating from the period AD 1450–1460 contain acidity peaks representing fallout of sulfuric acid onto both the Greenland and Antarctic ice caps. These acidity peaks have been attributed by others to the sedimentation of H₂SO₄ aerosols that originated from sulfur degassing during the Kuwae eruption. Improved dating techniques and new data from nineteen ice cores reveal a single acidity peak attributed to Kuwae lasting from 1453 to 1457. In this study, we present new electron microprobe analyses of the S, Cl, and F contents of matrix glasses and glass inclusions in phenocrysts from tephra ejected during the Kuwae eruption. We establish that the Kuwae event did indeed yield a large release of sulfur gases. From our glass inclusion data and analysis, we calculate that the total atmospheric aerosol loading from the 1452 Kuwae eruption was ≫100 Tg H₂SO₄. Much of the volatile mass released during the eruption was probably contained in a separate, volatile-rich, fluid phase within the pre-eruptive Kuwae magma body. Comparing the volatile release of the Kuwae eruption with other large-magnitude eruptions, places Kuwae as the greatest sulfuric acid aerosol producer in the last seven centuries, larger even than sulfur emissions from the eruption of Tambora (Indonesia) in 1815, and possibly Laki (Iceland) in 1783. The severe and unusual climatic effects reported in the mid- to late-1450s were likely caused by the Kuwae eruption.  相似文献   

大气季节内振荡的数值模拟 II. 全球变暖的影响     

俞永强  蒋国荣  何金海 《大气科学》2007,31(4):577-585

利用中国科学院大气物理研究所大气科学和地球流体力学数值模拟国家重点实验室（LASG）发展的耦合气候模式FGOALS1.0_g控制试验、二氧化碳（CO2）浓度加倍试验模拟结果及实测结果（NCEP/NCAR逐日再分析资料）研究了全球变暖对大气季节内振荡（ISO）特征变化的影响。通过对比分析控制试验、二氧化碳浓度加倍试验模拟结果及观测结果发现:（1）FGOALS1.0_g耦合气候模式具有一定的模拟季节内振荡的能力，主要表现为模式能够模拟出ISO活跃区的位置、中心位置的季节变动以及强度的季节变化，其缺陷是模拟的ISO强度偏弱，模拟的ISO周期不显著且偏高频；（2）实测资料诊断分析得到的近六十年来偏暖阶段ISO活跃区强度增强及范围扩大可能不是人类活动影响使温室气体增加所导致的，它可能是大气ISO本身的年代际尺度变化；（3）近六十年来纬向东传波（西传波）的能量的存在增长（减少）趋势的主要原因可能是人类活动影响引起温室气体增加所导致的；（4）由于FGOALS1.0_g耦合气候模式在模拟ISO主周期及强度方面时存在不足，因此实测结果诊断分析得到的偏暖阶段ISO小波能量强，主周期范围大，偏冷阶段反之的结论用FGOALS1.0_g耦合气候模式尚难以证实。  相似文献   

Mitigating Agricultural Emissions of Methane   总被引：7，自引：0，他引：7  

A.R. Mosier  J.M. Duxbury  J.R. Freney  O. Heinemeyer  K. Minami  D.E. Johnson 《Climatic change》1998,40(1):39-80

Agricultural crop and animal production systems are important sources and sinks for atmospheric methane (CH4). The major CH4 sources from this sector are ruminant animals, flooded rice fields, animal waste and biomass burning which total about one third of all global emissions. This paper discusses the factors that influence CH4 production and emission from these sources and the aerobic soil sink for atmospheric CH4 and assesses the magnitude of each source. Potential methods of mitigating CH4 emissions from the major sources could lead to improved crop and animal productivity. The global impact of using the mitigation options suggested could potentially decrease agricultural CH4 emissions by about 30%.  相似文献   

The role of anthropogenic activities in karst spring discharge volatility          下载免费PDF全文

Jing Wu  Jian Yin  Yonghong Hao  Yan Liu  Yonghui Fan  Xueli Huo  Youcun Liu  Tian‐Chyi J. Yeh 《水文研究》2015,29(13):2855-2866

The traditional hydrological time series methods tend to focus on the mean of whichever variable is analysed but neglect its time‐varying variance (i.e. assuming the variance remains constant). The variances of hydrological time series vary with time under anthropogenic influence. There is evidence that extensive well drilling and groundwater pumping can intercept groundwater run‐off and consequently induce spring discharge volatility or variance varying with time (i.e. heteroskedasticity). To investigate the time‐varying variance or heteroskedasticity of spring discharge, this paper presents a seasonal autoregressive integrated moving average with general autoregressive conditional heteroskedasticity (SARIMA‐GARCH) model, whose the SARIMA model is used to estimate the mean of hydrological time series, and the GARCH model estimates its time‐varying variance. The SARIMA‐GARCH model was then applied to the Xin'an Springs Basin, China, where extensive groundwater development has occurred since 1978 (e.g. the average annual groundwater pumping rates were less than 0.20 m³/s in the 1970s, reached 1.20 m³/s at the end of the 1980s, surpassed 2.0 m³/s in the 1990s and exceeded 3.0 m³/s by 2007). To identify whether human activities or natural stressors caused the heteroskedasticity of Xin'an Springs discharge, we segmented the spring discharge sequence into two periods: a predevelopment stage (i.e. 1956–1977) and a developed stage (i.e. 1978–2012), and set up the SARIMA‐GARCH model for the two stages, respectively. By comparing the models, we detected the role of human activities in spring discharge volatility. The results showed that human activities caused the heteroskedasticity of the Xin'an Spring discharge. The predicted Xin'an Springs discharge by the SARIMA‐GARCH model showed that the mean monthly spring discharge is predicted to continue to decline to 0.93 m³/s in 2013, 0.67 m³/s in 2014 and 0.73 m³/s in 2015. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Does the Port 2000 harbour construction have an effect on the Seine estuary suprabenthic community?     

Jean-Claude Dauvin  Sandrine Alizier  Carole Vallet  Thierry Ruellet 《Estuarine, Coastal and Shelf Science》2010

Using a Before/During/After protocol, the effects of Port 2000 (the Le Havre harbour extension) on the suprabenthic communities in the Northern Channel of the Seine estuary (English Channel) were examined from March 2001 to March 2009. Since the beginning of Port 2000 construction in 2002, there have been several changes in the hydrological and sedimentary characteristics in the North Channel, including changes in current velocity, bottoms salinity and sand accumulation, as well as in the benthic communities themselves, moving from mud to medium and coarse sand communities. For the suprabenthos, changes were moderate, corresponding to an increase in species richness in the upper-part of the North Channel and a decrease in species density in the dominant mysids species (i.e., mainly Mesopodospsis slabberi) over time. Due to hydrological changes since the beginning of the Port 2000 project (several years of low freshwater input) it has been difficult to attribute the biological changes to Port 2000 construction only. In the future, the results obtained for the suprabenthos will have to be compared to those obtained for the macrobenthos. Similarly, since the suprabenthos is known to play an important role in the estuarine trophic chain, it will also be essential to estimate the fish distribution in the North Channel and to examine their stomach contents to evaluate the probable changes since the Port 2000 project began.  相似文献   

ESTIMATE OF METHANE EMISSIONS FROM RICE FIELDS IN CHINA BY CLIMATE-BASED NET PRIMARY PRODUCTIVITY     

KANG Guo-ding    CAI Zu-cong  ZHANG Zi-heng    XIAO Peng-feng 《中国地理科学(英文版)》2004,14(4):326-331

1INTRODUCTIONIrrigated ricefieldsarecharacterizedbylargespatialandtemporalvariationsin CH4 emissiontotheatmo-sphere.Accordingly,thereisagreatuncertaintyintheestimate ofCH4 emissionsfromricefields.GreateffortshavebeenmadetoestimatetheCH4 emissionsfromricefieldsandseveralapproacheshavebeendeveloped.TherepresentativemethodsincludetheIPCC(Inter-governmentPanelofClimateChange)region-specificemissionfactormethodandthemodelcalculationmethod.Toimprovethecalculationaccuracy,theIPCCmethodreq…  相似文献   

中国居民食物消费碳排放时空演变趋势及其驱动机制分析     

曹志宏  郝晋珉  邢红萍 《地理科学进展》2020,39(1):91-99

食物生产是影响温室效应气体排放的重要方面,由于食物类型不同其碳排强度存在较大的差异,因此当前中国居民食物消费快速演替必然会对生态碳环境产生重要影响。论文利用洛伦兹曲线和基尼系数,研究1997—2016年中国城乡居民食物消费在生产过程中碳排放时空演变及其主要驱动因子。主要结论如下：① 在数量上,中国居民食物消费碳排放总量和人均量整体都呈现逐渐的增长刚性,但仍属于低碳消费模式;② 在结构上,各类型食物碳排放演变呈现显著的分异态势,整体上动物性食物碳排放增长速度快于植物性食物碳排放减少速度;③ 在城乡差异上,城镇和乡村居民食物消费碳排放在数量、结构和趋势上表现出显著的城乡二元属性,但近年城乡差异表现出减缓趋势;④ 在空间上,各地食物消费碳排放呈现较显著的民族性、地域性、集聚性和中心“塌陷”的特征,碳排放密度高值主要分布在直辖市和沿海经济相对发达地区;⑤ 在驱动力上,结构演替是全国居民食物消费碳排放总量整体变化的主要驱动因素,而人口数量是各地地域空间差异分布的主要驱动因子。  相似文献